Calcite I

Despite its wide distribution in limestone and as a common gangue mineral in ore deposits, the rainbow of colors and beautiful crystal forms of calcite, from locations around the world, have made it a favorite of collectors. One such favorite is the group of calcite crystals, tipped by hematite, from the Egremont Mine shown in Figure 1. In massive form it has provided lapidists and other artisans a beautiful material for the creation of jewelry and other artworks, such as the sculpture done in Utah calcite, shown in Figure 2.

In this blog I will briefly describe the mechanical properties of calcite, its crystallography, optical properties, and sources of its colors. In Calcite II, I will follow with a gallery of calcite specimens sought by collectors from world-wide locations.

Figure 1. Calcite with a partial hematite coating, Egremont Mine,
Cumberaland, England [Ref 1]
Figure 2. Abstract calcite sculpture “Sundance” carved from Utah calcite [Ref 2].

Mechanical Properties [Ref 3]

The hardness of calcite on the Mohs Scale is 3. It’s brittle because of its perfect cleavage along rhombohedral planes. It parts readily, along twin planes formed by stresses. It can also exhibit conchoidal fracture.

Crystallography [Ref 3, 4]

Calcite crystallizes in the Trigonal System with crystallographic axes, and the often-seen rhombohedral, (Left), and scalenohedral, (Right), forms, shown in Figure 1 [Ref 4]. The system possesses three a1,2,3-axes at 120 degrees with respect to each other in the horizontal plane and the perpendicular c-axis. Other crystal forms can be seen in Ref 3.

Any plane through the trigonal lattice is represented by four numbers (hkmi). These are the Miller Indices which are the reciprocal values of the intercepts respectively on the a1, a2, a3, and c-axis. A family of planes is indicated by the notion {hkmi}.

Calcite forms twinned crystals according to four twin laws [Figure 4 in Ref 5] as shown in Figure 2. The twin forms and the associated family of planes are given in Table I. The angles between the vertical c-axes for each twin form are respectively to the nearest degree of 180, 127, 90, and 53. Calcite specimens exhibiting the twin laws are shown in Figures 5-8.

Among minerals calcite can be considered to be the best one to demonstrate cleavage because of its perfect cleavage along the rhombehedral family of planes {10-11}. The rhombehedral shape of the specimen demonstrating birefringence (double refraction) is evident in Figure 10.

Figure 3. Trigonal Crystallographic System [Ref 4]

Figure 4. Four twin laws of calcite shown with scalenohedral forms [Ref 5]

                                             TABLE 1

                        Twin Form                 Family of Twin planes
                               a                                {0001}
                              b                               {10-11}
                               c                               {01-12}
                               d                               {02-21}
Figure 5. Calcite crystal twinned on the basal (0001) plane,
Elmwood Mine, Carthage County, Tennessee [Ref 6].
Figure 6. Calcite crystal twinned on the rhombahedral plane
(10-11) [Ref 7].
Figure 7. Calcite crystal twinned on the pyramidal plane (01-12) location not stated [Ref 8].
Figure 8. Calcite crystal twinned on the pyramidal plane (02-21)
Brushy Creek mine, Reynolds County, Missouri [Ref 9].

Optical Properties 

Calcite exhibits a range of lusters between vitreous to pearly and its transparency ranges between transparent to translucent. Calcite also exhibits birefringence in its refraction of light within the crystal [Ref 3]. Because the refractive index of calcite varies with the direction of light within a calcite crystal the light entering the crystal is doubly refracted into two different directions, as shown schematically in Figure 3 and demonstrated by the double image of the lines seen in Figure 4.

Figure 9. Double refraction in calcite showing two light paths [Ref 10].
Figure 10. Doubly refracted light in a calcite rhombahedron [Ref 11]

Sources of Color in Calcite 

In its description of the properties of calcite, the mineral reference site mindat lists besides white, a rainbow of colors: yellow, red, orange, blue, green, brown, grey, etc. for calcite.

Calcite, which chemically is calcium carbonate with the formula CaCO3, is colorless when pure, as shown by the crystals on matrix shown in Figure 7 [Ref 12].  The rich colors of calcite specimens arise from different sources, such as substitution of low levels of one of the transition metals its divalent ionic form M+2for the calcium ion Ca+2in the lattice of the crystal, low densities of radiation-induced defects in the lattice of the crystal, or inclusions of a pigmented mineral. 

Colors due to transition metal impurity ions [Ref A]

The colors present with iron and chromium, manganese, cobalt, or chromium present in, respectively ferroan, manganoan, cobaltoan, and chromian calcites are summarized in Table II. The yellow, pink and green colors due to these transmission metals can be seen also in many other minerals as can be seen in a search on the Web. 

                                                                        TABLE II

                             MINERAL                               COLOR
                         Ferroan Calcite                               Yellow
                       Cobaltoan Calcite                                 Pink
                     Manganoan Calcite                                 Pink
                        Chromian Calcite                                Green

Colors arising from radiation damage in the crystal lattice 

The search on the web for what colors of calcite might stem from radiation damage disclosed two references in which blue and amber-colored calcite were associated with radiation damage. Results of the study of References suggested that radiation-induced color centers involving the negative ion CO-3and the presence of stress-induced twInning and lattice disloctions account for the coloring mechanism.

The Mineral Spectroscopy Server of the Divisions of Geological and Planetary Sciences of the California Institute of Technology states that natural radiation induces an amber color in the Calcites from the lead-zinc Tri-State Mining District [Ref B, C]

Colors arising from colored inclusions 

Colorful calcite is also produced by the presence of pigmented inclusions. Clear and transparent crystals of calcite, when included by such strongly colored minerals as malachite, pyrite, hematite, native calcite and others, make highly aesthetic specimens. The inclusions may be dispersed in the cystal (Figure 16) or reside on an included phantom crystal within the specimen crystal (Crystal 17).

Calcite, Bigrigg Mine, Egremont area, West Cumberland Mining District, Cumbria, England [Ref 12]
Figure 12. Ferroan calcite, Boral Limited quarry, Bundoora, City of Whittlesea, Victoria, Australia [Ref 13]
Figure 13. Manganoan calcite, 2ndSovietsky Mine, Dal’ngorsk, Far Eastern Russia [Ref 14]
Figure 14. Cobaltoan calcite with green kolwezite, Kambove Mine, Katanga Copper district, Democratic Republic of Congo [Ref 15].
Figure15. Bladed crystals of chromian calcite, Santa Eulalia District, Chihuahua, Mexico [Ref 16].

Color due to an included pigmented mineral 

Figure 16. Calcite with conichalcite inclusions, Mapimi district, Durango, Mexico [Ref 17].
Figure 17. Calcite crystals containing phantom crystals covered with marcasite, Linwood Mine, Buffalo, Scott County, Iowa [Ref 18].

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